Metal-Organic Insertion/Light Initiated Radical (MILRad) Polymerization

Thermoplastic elastomers are the most important and widely used polymeric materials to date. We are exploring novel synthetic pathways to afford a more practical and easier access to functionalized and specialized thermoplastics. This research effort involves the investigation of the photoactivation of metal organic catalysts with a variety of monomers also in combination with other known polymerization pathways.